PHOSPHINDOLYL ANIONS BY ELIMINATION FROM 1-PHOSPHOALLYLLITHIUM COMPLEXES - ETA(5) AND ETA(3) COORDINATION OF A PHOSPHOLYL FRAGMENT

被引：31

作者：

NIECKE, E

NIEGER, M

WENDEROTH, P

机构：

[1] Anorganisch-chemisches Institut, Universität Bonn, D-53121

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 03期

关键词：

D O I：

10.1002/anie.199403531

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A phosphindolyllithium complex or a lithium salt with a phosphindolyl anion? Both the ease of the synthesis and the structure of compounds 1 are surprising: the unit cell of crystalline 1 b contains two independent molecules in which lithium is coordinated in an η5 fashion in one and an η3 fashion in the other—this indicates the transition from the complex to the anion. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：353 / 354

页数：2

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