THE FORMATION OF DISTANNANES FROM TIN HYDRIDES

被引：25

作者：

DAVIES, AG

OSEIKISSI, DK

机构：

[1] Chemistry Department, University College London, 20 Gordon Street

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 474卷 / 1-2期

关键词：

TIN; HYDRIDE; FREE RADICALS; HYDROSTANNATION; HYDROSTANNOLYSIS;

D O I：

10.1016/0022-328X(94)84073-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The disproportionation of a dialkyltin hydride R2SnXH (X = halide or carboxylate) to give H-2 and XR2SnSnR2X follows a radical chain mechanism, which may involve homolytic displacement by a tin radical of a hydrogen atom from a tin centre.

引用

页码：C8 / C10

页数：3

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