NEAR-INFRARED SPECTRA OF BACL2.2D2O AT 10 K - A LOCAL-MODE APPROACH

被引：5

作者：

MCCARTHY, PJ ^{[1
]}

WALKER, IM ^{[1
]}

机构：

[1] YORK UNIV, N YORK M3J 1P3, ONTARIO, CANADA

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 13期

关键词：

D O I：

10.1021/ic00013a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polarized crystal spectra of BaCl2.2D2O and of several partially deuterated crystals have been measured at 10 K in the near-infrared region. The O-D stretching bands have been analyzed by using local-mode theory, and the calculated parameters are compared with those derived from BaCl2.2H2O. The anharmonicities are smaller than those observed for O-H oscillators in bound H2O; this trend follows that found in the gas-phase molecules. The local-mode parameters for O-H oscillators in HOD are not the same as those in H2O. Some possible explanations for this are presented.

引用

页码：2772 / 2776

页数：5

共 20 条

[1] LOW TEMPERATURE STUDY OF SELF-ASSOCIATED ALCOHOLS IN NEAR-INFRARED [J].