MATRIX REACTIONS OF P-4 AND P-2 WITH O-3 MOLECULES

被引:32
作者
ANDREWS, L
MCCLUSKEY, M
MIELKE, Z
WITHNALL, R
机构
[1] Chemistry Department, University of Virginia, Charlottesville
关键词
D O I
10.1016/0022-2860(90)80008-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Matrix reaction of P4 and P2 with isotopic ozone molecules have been studied using both heated GaP and discharge of P4 from white phosphorus as sources of P2. Isotopic shifts and multiplets support identification of P4O terminal and bridged isomers, PO, PO2, P2O, P2O2, P2O3, P2O4, and P2O5 in these experiments. © 1990.
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页码:95 / 108
页数:14
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