THE PHOTOELECTROCHEMICAL OXIDATION OF BIS(BENZYLIDENE)ACENAPHTHENE

被引：6

作者：

COMPTON, RG ^{[1
]}

FISHER, AC ^{[1
]}

WELLINGTON, RG ^{[1
]}

WINKLER, J ^{[1
]}

BETHELL, D ^{[1
]}

LEDERER, P ^{[1
]}

机构：

[1] UNIV LIVERPOOL, DEPT CHEM, LIVERPOOL L69 3BX, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 08期

关键词：

D O I：

10.1039/p29920001359

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of bis(benzylidene)acenaphthene in acetonitrile solution at platinum electrodes irradiated with light (377 nm) has been investigated using a combination of channel electrode and spectrofluorimetric voltammetries. The efficient formation of the highly fluorescent molecule 7-phenylbenzo[k]fluoranthene was demonstrated and the electrode reaction mechanism characterised as of the `photo-CE' type. Kinetic parameters relating to this process are reported.

引用

页码：1359 / 1362

页数：4

共 14 条

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