SYNTHESIS, PROPERTIES AND REACTIVITY OF METAL HETEROCYCLIC-COMPOUNDS .86. COBALT-INDUCED SYNTHESIS OF A THIADIPHOSPHOLE

被引：13

作者：

LINDNER, E

SCHLENKER, T

HAASE, C

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 01期

关键词：

COBALT; THIADIPHOSPHOLE;

D O I：

10.1016/0022-328X(94)87029-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

3,5-Di-tert-butyl-1-thia-2,4-diphosphole (3) has been formed by insertion of (t)BuC=P (2) into the P - S bond of the (eta(2)-thiophosphinito)cobalt complex (OC)(2)Ph(3)PCo(eta(2)-PEt(2) --S) (1), followed by [2+2] cycloaddition of the resulting intermediate (OC)(2)Ph(3)PCoPEt(2)-P=C((t)Bu)-S with a second phosphaalkyne 2 and elimination of the (OC)(2)Ph(3)PCoPEt(2) fragment.

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页码：C31 / C32

页数：2

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