ELECTRICAL-RESISTIVITY MEASUREMENTS ON SOME R5SI3 PHASES - R = GD, TB, YB, LU AND Y

被引:33
作者
CANEPA, F
CIRAFICI, S
MERLO, F
PALENZONA, A
机构
[1] Istituto di Chimica Fisica, C.so Europa 26, Università di Genova, Genova
关键词
D O I
10.1016/0304-8853(93)90175-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The electrical resistivity of the R5Si3 phases with R = Gd, Th, Yb, Lu, Y has been measured in the 10-800 K temperature range. The compounds of Gd and Th exhibit one transformation point, which can be ascribed to magnetic transitions. The temperature dependence of the resistivity of Y5Si3 and Lu5Si3 has been described by a combination of the phonon contribution and an interband scattering term. For Yb5Si3, the different behaviour in the electrical resistivity, the low value of the magnetic moment as well as the anomalous values of the elementary cell constants can be explained assuming a mixed valent state of Yb: a divalent Yb ion in one site set and a trivalent Yb ion in the other site.
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页码:182 / 186
页数:5
相关论文
共 17 条
[1]   PHOTOEMISSION-STUDIES OF MIXED-VALENCE IN YB3SI5, YBSI AND YB5SI3 - EQUIVALENT VERSUS INEQUIVALENT YB SITES [J].
ABBATI, I ;
BRAICOVICH, L ;
CARBONE, C ;
NOGAMI, J ;
LINDAU, I ;
IANDELLI, I ;
OLCESE, G ;
PALENZONA, A .
SOLID STATE COMMUNICATIONS, 1987, 62 (01) :35-39
[2]  
ALSTAD S, 1961, PHYS REV, V123, P418
[3]   THERMAL CONDUCTIVITIES AND LORENZ FUNCTIONS OF DY,ER AND LU SINGLE CRYSTALS [J].
BOYS, DW ;
LEGVOLD, S .
PHYSICAL REVIEW, 1968, 174 (02) :377-&
[4]   MAGNETIC-PROPERTIES OF SOME RARE-EARTH SILICIDES - GDSI, GD5SI3, DY5-XNDXSI3 [J].
GANAPATHY, EV ;
KUGIMIYA, K ;
STEINFINK, H ;
TCHERNEV, DI .
JOURNAL OF THE LESS-COMMON METALS, 1976, 44 (JAN) :245-258
[5]  
GLADYSHEVSKII EI, 1971, CRYSTAL CHEM INTERME
[6]  
Iandelli A., 1979, Handbook on the physics and chemistry of rare earths, vol.2. Alloys and intermetallics, P1
[7]   ELECTRICAL-RESISTIVITY OF LA [J].
LEGVOLD, S ;
BURGARDT, P ;
BEAUDRY, BJ ;
GSCHNEIDNER, KA .
PHYSICAL REVIEW B, 1977, 16 (06) :2479-2481
[8]  
MEADEN GI, 1965, ELECTRICAL RESISTANC
[9]   ELECTRICAL-RESISTIVITY OF SOME LAAG,CEAG,YAG EQUIATOMIC COMPOUNDS [J].
MERLO, F ;
CANEPA, F .
JOURNAL OF PHYSICS F-METAL PHYSICS, 1987, 17 (12) :2373-2376
[10]  
MOTT NF, 1958, THEORY PROPERTIES ME, P240