NEW HOMOCHIRAL BINAPHTHOL-MODIFIED ORGANOLANTHANIDE REAGENTS FOR THE ENANTIOSELECTIVE ADDITION TO ALDEHYDES

被引：19

作者：

CHIBALE, K ^{[1
]}

GREEVES, N ^{[1
]}

LYFORD, L ^{[1
]}

PEASE, JE ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,ROBERT ROBINSON LABS,LIVERPOOL L69 3BX,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)82211-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Optically active secondary alcohols were obtained in high chemical yield and optical purity (up to 85% ee) from the lanthanide-mediated enantioselective addition of alkyl nucleophiles to aromatic aldehydes.

引用

页码：2407 / 2410

页数：4

共 20 条

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