A STABLE TITANACYCLO-2-PENTENE - SYNTHESIS AND STRUCTURE OF 3,3-BIS(ETA-5-CYCLOPENTADIENYL)-4,5-DIPHENYL-3-TITANATETRACYCLO-[5.5.1.0/2,6/.0/8,12]TRIDECA-4,8,11-TRIENE

被引：8

作者：

BHIDE, VV

FARONA, MF

DJEBLI, A

YOUNGS, WJ

机构：

[1] UNIV AKRON,DEPT CHEM,AKRON,OH 44325

[2] CASE WESTERN RESERVE UNIV,DEPT CHEM,CLEVELAND,OH 44106

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 06期

关键词：

D O I：

10.1021/om00156a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound was synthesized by the reduction of Cp2TiCl2 with Mg in the presence of tricy-clo[5.2.1.02’6]deca-2,5,8-triene and diphenylacetylene. The compound crystallizes in the orthorhombic space group P212l2l with α = 8.447 (2) Â, b = 18.389 (4) Â, c = 19.210 (4) A, and V = 2984 (1) Â.3 The final agreement for all data was R(F) = 5.73%. Η and13C NMR spectral assignments are made with the aid of 2D-COSY and HETCOR NMR studies.f X-ray structure determination. © 1990, American Chemical Society. All rights reserved.

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页码：1766 / 1769

页数：4

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