TETRAKIS(PYRIDINE)SILVER(II) PEROXODISULFATE, [AG(PY)4]S2O8, A REAGENT FOR THE OXIDATIVE TRANSFORMATIONS

被引：21

作者：

FIROUZABADI, H

SALEHI, P

MOHAMMADPOURBALTORK, I

机构：

[1] Chemistry Department, Shiraz University, Shiraz

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 10期

关键词：

D O I：

10.1246/bcsj.65.2878

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrakis(pyridine)silver(II) peroxodisulfate oxidizes aromatic aldehydes to carboxylic acids, benzylic alcohols to carbonyl compounds, aromatic thiols, and allylaryl thioethers to arylsulfonic acids and benzylic carbon-hydrogen bonds to carbonyl groups. alpha-Hydroxycarboxylic acids and phenylacetic acids are decarboxylated to produce carbonyl compounds. Dibenzyl ether and its sulfur analogue are converted to their corresponding ester and the thioester, respectively.

引用

页码：2878 / 2880

页数：3

共 33 条

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