MODEL STUDIES TOWARDS THE INSECT ANTIFEEDANT JODRELLIN-A USING AN ORGANOSELENIUM MEDIATED CYCLIZATION REACTION

被引：15

作者：

BLANEY, WM

CUNAT, AC

LEY, SV

MONTGOMERY, FJ

SIMMONDS, MSJ

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV LONDON BIRKBECK COLL,DEPT BIOL,LONDON WC1E 7HX,ENGLAND

[3] ROYAL BOT GARDENS,JODRELL LAB,RICHMOND TW9 3AE,SURREY,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)76988-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An organoselenium mediated cyclization reaction of a beta-ketolactone (5), was used as the key step in an efficient synthesis of the molecular skeleton of the insect antifeedant Jodrellin A (1). The model compound (2) shows significant activity against the African leaf worm Spodoptera littoralis, at 1000 ppm.

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收藏

页码：4861 / 4864

页数：4

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