STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .10. SOLVOLYSIS OF "1-(P-CYCLOPROPYLPHENYL)-1-ARYLETHYL AND 1-(P-ISOPROPYLPHENYL)-1-ARYLETHYL CHLORIDES - TEST OF TOOL OF INCREASING ELECTRON DEMAND TO SYSTEMS WITH RELATIVELY SMALL ELECTRONIC RESPONSE

被引：23

作者：

BROWN, HC ^{[1
]}

RAVINDRANATHAN, M ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB,W LAFAYETTE,IN 47907

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1975年 / 97卷 / 10期

关键词：

D O I：

10.1021/ja00843a047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2895 / 2898

页数：4

共 17 条

[1] BROWN H, COMMUNICATIONS
[2] ADDITIONS TO BICYCLIC OLEFINS .7. ELECTROPHILIC ADDITION OF HYDROGEN-CHLORIDE AND DEUTERIUM CHLORIDE TO NORBORNENE, 2-METHYLENENORBORNANE, AND RELATED BICYCLIC OLEFINS - EVIDENCE FOR A CARBONIUM-ION PROCESS AND CAPTURE OF UNSYMMETRICAL (CLASSICAL) 2-NORBORNYL CATIONS
BROWN, HC
LIU, KT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (03) : 600 - 610
[3] SOLVOLYSIS OF 2-[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-2-NORBORNYL P-NITROBENZOATES AND 1-ARYLCYCLOPENTYL P-NITROBENZOATES - FAILURE OF A FURTHER INCREASE IN ELECTRON DEMAND TO ALTER EXO-ENDO RATE RATIO
BROWN, HC
RAVINDRANATHAN, M
TAKEUCHI, KI
PETERS, EN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (10) : 2899 - 2900
[4] SOLVOLYSIS OF 2-ARYL-5-METHYL-2-NORBORNENYL PARA-NITROBENZOATES - EVIDENCE FOR PI PARTICIPATION AS A FACTOR IN VARIATION OF RATES AND PRODUCTS WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER
BROWN, HC
RAVINDRA.M
PETERS, EN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (23) : 7351 - 7352
[5] SOLVOLYSIS OF 2-ARYL-6-METHOXYBENZONORBORNEN-2-YL P-NITROBENZOATES CONTAINING REPRESENTATIVE SUBSTITUENTS IN 2-ARYL GROUP . VARIATION IN EXO/ENDO RATE RATIO WITH ELECTRON DEMAND OF 2-ARYL GROUP
BROWN, HC
LIU, KT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (21) : 5909 - &
[6] RATES OF SOLVOLYSIS OF THE ALKYLPHENYLDIMETHYLCARBINYL CHLORIDES - EVIDENCE FOR THE IMPORTANCE OF CARBON-TO-CARBON HYPERCONJUGATIVE CONTRIBUTIONS IN ALKYL GROUPS
BROWN, HC
BRADY, JD
GRAYSON, M
BONNER, WH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (08) : 1897 - 1903
[7] STERIC INHIBITION OF INTERACTION OF A CYCLOPROPYL SUBSTITUENT WITH ELECTRON-DEFICIENT CENTER IN SOLVOLYSIS OF T-CUMYL DERIVATIVES
BROWN, HC
CLEVELAN.JD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (09) : 2051 - &
[8] A CONVENIENT PROCEDURE FOR QUANTITATIVE CONVERSION OF REACTIVE ALCOHOLS AND OLEFINS INTO CORRESPONDING CHLORIDES
BROWN, HC
REI, MH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (04) : 1090 - &
[9] HIGH EXO - ENDO RATE RATIO AND PREDOMINANT EXO SUBSTITUTION IN SOLVOLYSIS OF 2-P-ANISYLNORBORNYL DERIVATIVES . CHARACTERISTICS OF A HIGHLY STABILIZED CLASSICAL NORBORNYL CATION
BROWN, HC
TAKEUCHI, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (10) : 2691 - &
[10] BROWN HC, 1968, J AM CHEM SOC, V90, P2693

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