REGIOSPECIFIC SYNTHESIS OF AZA-BETA-LACTAMS FROM DIAZIRIDINES

被引:32
作者
ALPER, H
DELLEDONNE, D
KAMEYAMA, M
ROBERTO, D
机构
[1] Ottawa-Carleton Chemistry Institute, Department of Chemistry, University of Ottawa, Ottawa, Ontario
关键词
D O I
10.1021/om00117a035
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
1,3-Diazetidinones are obtained by bis(dibenzylideneacetone)palladium(0)-catalyzed carbonylation of diaziridines having one substituent attached to the ring carbon atom. This regiospecific insertion into the nitrogen-nitrogen bond also occurs for 3,3-disubstituted diaziridines, provided one uses stoichiometric quantities of cobalt carbonyl. © 1990, American Chemical Society. All rights reserved.
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页码:762 / 765
页数:4
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