BUILDING-BLOCKS FOR THE SYNTHESIS OF ENANTIOMERICALLY PURE JASMONOIDS - SYNTHESIS OF (+)-METHYL EPIJASMONATE

被引：47

作者：

HELMCHEN, G

GOEKE, A

LAUER, G

URMANN, M

FRIES, J

机构：

[1] Organisch-Chemisches Institut, Universität Heidelberg, D-6900

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1990年 / 29卷 / 09期

关键词：

D O I：

10.1002/anie.199010241

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Jasmine oil contains only 5% of the active constituent methyl epijasmonate (1a) in equilibrium with methyl jasmonate (1b). Multigram quantities of 1a can be synthesized in a highly diastereoselective fashion from the fumarate of (S)‐ethyl lactate and cyclopentadiene. The intermediates thereby obtained can serve as building blocks for the synthesis of nearly all jasmonoids. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

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页码：1024 / 1025

页数：2

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