CHARGE MOSAIC COMPOSITE MEMBRANES CONSTRUCTED BY PHASE GROWTH

被引：13

作者：

ISHIZU, K

AMEMIYA, M

机构：

[1] Department of Polymer Science, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152, 2-12, Ookayama

来源：

JOURNAL OF MEMBRANE SCIENCE | 1990年 / 54卷 / 1-2期

关键词：

D O I：

10.1016/S0376-7388(00)82071-2

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A template pattern with alternating poly(4-vinylpyridine) (P4VP)/poly(vinyl alcohol) (PVA) lamellae was fabricated upon a microporous membrane by casting of poly [4-vinylpyridine (4VP) g-vinyl alcohol (VA)] graft copolymer from a water-1-propanol mixture. After treatment involving binding of the microporous membrane with graft copolymer and also domain fixing of the PVA phases, a dilute solution of [sodium p-styrenesulfonate (SSS)-2-hydroxyethyl methacrylate (HEMA)] copolymer/P4VP binary blend was cast on this template surface. The (SSS-HEMA) copolymer/P4VP binary microdomains formed by phase growth were oriented perpendicularly to the film surface. After chemical treatments (introduction of a positive charge and domain fixing of ion exchange regions), we examined the transport of KCl and glucose through this charge mosaic composite membrane. © 1990.

引用

页码：75 / 87

页数：13

共 21 条

[1] POLY(STYRENE-B-BUTADIENE-B-4-VINYLPYRIDINE) 3-BLOCK POLYMERS - SYNTHESIS, CHARACTERIZATION, MORPHOLOGY, AND MECHANICAL-PROPERTIES [J].

ARAI, K ;

KOTAKA, T ;

KITANO, Y ;

YOSHIMURA, K .

MACROMOLECULES, 1980, 13 (06) :1670-1678

[2] THE FLORY CONSTANTS FOR POLY-4-VINYLPYRIDINE IN ETHANOL [J].

BERKOWITZ, JB ;

YAMIN, M ;

FUOSS, RM .

JOURNAL OF POLYMER SCIENCE, 1958, 28 (116) :69-82

[3] A UNIVERSAL CALIBRATION FOR GEL PERMEATION CHROMATOGRAPHY [J].

GRUBISIC, Z ;

REMPP, P ;

BENOIT, H .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1967, 5 (9PB) :753-&

[4] DOMAIN-BOUNDARY STRUCTURE OF STYRENE-ISOPRENE BLOCK CO-POLYMER FILMS CAST FROM SOLUTION .4. MOLECULAR-WEIGHT DEPENDENCE OF LAMELLAR MICRODOMAINS [J].

HASHIMOTO, T ;

SHIBAYAMA, M ;

KAWAI, H .

MACROMOLECULES, 1980, 13 (05) :1237-1247

[5] THEORY OF UNSYMMETRIC POLYMER-POLYMER INTERFACES [J].

HELFAND, E ;

SAPSE, AM .

JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (04) :1327-1331

[6]

HELFAND E, 1971, J CHEM PHYS, V56, P3592

[7] ARTIFICIAL MEMBRANES FROM MULTIBLOCK COPOLYMERS .5. TRANSPORT BEHAVIORS OF ORGANIC AND INORGANIC SOLUTES THROUGH A CHARGE-MOSAIC MEMBRANE [J].

HIRAHARA, K ;

TAKAHASHI, S ;

IWATA, M ;

FUJIMOTO, T ;

MIYAKI, Y .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1986, 25 (02) :305-313

[8]

ISHIZU K, 1988, MAKROMOL CHEM-RAPID, V9, P317

[9]

ISHIZU K, 1987, MAKROMOL CHEM-RAPID, V8, P39

[10]

ISHIZU K, 1988, MAKROMOL CHEM, V189, P2875

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