FORMATION, CRYSTAL-CHEMISTRY AND MAGNETISM OF COMPOUNDS RE(2)TGE(6), RE=RARE EARTH, T=PD, PT, CU, AG AND AU

被引：48

作者：

SOLOGUB, O

HIEBL, K

ROGL, P

BODAK, OI

机构：

[1] UNIV VIENNA,INST PHYS CHEM,A-1090 VIENNA,AUSTRIA

[2] LVOV IVAN FRANKO STATE UNIV,INST INORGAN CHEM,290005 LVOV,UKRAINE

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1995年 / 227卷 / 01期

关键词：

TERNARY COMPOUNDS; X-RAY POWDER DIFFRACTION; ANTIFERROMAGNETIC COMPOUNDS;

D O I：

10.1016/0925-8388(95)01617-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel ternary compounds RE(2)TGe(6) (RE=Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb; T=Pd, Pt, Ag, Au) were synthesized by argon are melting followed by a heat treatment at 600 or 800 degrees C for 150 h. From X-ray powder analysis all compounds were found to be isotypic with structure type Ce,CuGe6. Magnetic susceptibilities were measured for RE(2)CuGe(6) (RE = Ce, Pr, Nd, Sm) and Ce(2)dGe(6). All compounds exhibit antiferromagnetic ordering below 20 K. The paramagnetic effective moments agree with the values for tripositive RE ion moments. The Sm containing sample reveals typical Van Vleck type paramagnetism above the Neel point.

引用

页码：37 / 39

页数：3