CONTRASTING BEHAVIOR OF RELATED PALLADIUM COMPLEX-DERIVED RESOLVING AGENTS - 8-H CONFORMATIONAL LOCKING OF THE 1-NAPHTHYL SIDE-CHAIN

被引：90

作者：

ALCOCK, NW

HULMES, DI

BROWN, JM

机构：

[1] DYSON PERRINS LAB,OXFORD OX1 3QY,ENGLAND

[2] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 03期

关键词：

D O I：

10.1039/c39950000395

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray crystal structures of palladium complexes 4 and 6 derived from (R)-N,N-dimethyl-1-(1-naphthyl)ethylamine and (S)-N,N-dimethyl-1-phenylethylamine, respectively, are reported; in the latter case two diastereoisomers differing both in the ligand configuration and the conformation of the C,N-chelate ring cocrystallise as a quasiracemate.

引用

收藏

页码：395 / 397

页数：3

相关论文

共 21 条

[1] SYNTHESIS AND RESOLUTION OF 1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE - A P-N CHELATING LIGAND FOR ASYMMETRIC CATALYSIS [J].

ALCOCK, NW ;

BROWN, JM ;

HULMES, DI .

TETRAHEDRON-ASYMMETRY, 1993, 4 (04) :743-756

[2] RESOLUTIONS INVOLVING METAL COMPLEXATION - PREPARATION AND RESOLUTION OF (R,S)-METHYLPHENYL(8-QUINOLYL)PHOSPHINE AND ITS ARSENIC ANALOG - CRYSTAL AND MOLECULAR-STRUCTURE OF (+)589-[(R)-DIMETHYL(1-ETHYL-ALPHA-NAPHTHYL)AMINATO-C-2, N][(S)-METHYLPHENYL(8-QUINOLYL)PHOSPHINE]PALLADIUM(II) HEXAFLUOROPHOSPHATEOG [J].

ALLEN, DG ;

MCLAUGHLIN, GM ;

ROBERTSON, GB ;

STEFFEN, WL ;

SALEM, G ;

WILD, SB .

INORGANIC CHEMISTRY, 1982, 21 (03) :1007-1014

[3] MECHANISTIC AND SYNTHETIC STUDIES IN CATALYTIC ALLYLIC ALKYLATION WITH PALLADIUM COMPLEXES OF 1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE [J].

BROWN, JM ;

HULMES, DI ;

GUIRY, PJ .

TETRAHEDRON, 1994, 50 (15) :4493-4506

[4] EFFECTIVE ASYMMETRIC HYDROBORATION CATALYZED BY A RHODIUM COMPLEX OF 1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE [J].

BROWN, JM ;

HULMES, DI ;

LAYZELL, TP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (22) :1673-1674

[5] STEREOCHEMICAL INVESTIGATIONS OF COORDINATED SULFUR STEREOCENTERS - X-RAY STRUCTURES OF DIASTEREOMERS OF (-)589-[PD((R)-CH3CH(1-C10H6)NME2-C2,N)(R/S)-(PH2PCH2SME-P,S)]PF6 [J].

CHOOI, SYM ;

HOR, TSA ;

LEUNG, PH ;

MOK, KF .

INORGANIC CHEMISTRY, 1992, 31 (08) :1494-1500

[6] 1,1'-BI-ISOQUINOLINE - A CHIRAL BIDENTATE N-DONOR LIGAND WITH C2-SYMMETRY - FORMATION OF OPTICALLY-ACTIVE COMPLEXES WITH HIGH CHIRAL RECOGNITION [J].

DAI, LX ;

ZHOU, ZH ;

ZHANG, YZ ;

NI, CZ ;

ZHANG, ZM ;

ZHOU, YF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (23) :1760-1762

[7]

GLADIALI S, 1994, TETRAHEDRON-ASYMMETR, V4, P511

[8] ENANTIOSELECTIVE BIOTRANSFORMATION OF ETHYL-NORMAL-PROPYLARSINIC ACID BY THE MOLD SCOPULARIOPSIS-BREVICAULIS - ASYMMETRIC-SYNTHESIS OF (R)-ETHYLMETHYL-NORMAL-PROPYLARSINE [J].

GUGGER, P ;

WILLIS, AC ;

WILD, SB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (17) :1169-1170

[9]

JACQUES J, 1991, ENANTIOMERS RACEMATE, P100

[10] EFFICIENT SYNTHESIS OF (R)-(6,6'-DIFLUOROBIPHENYL-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE) AND (S)-(6,6'-DIFLUOROBIPHENYL-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE) - ELECTRON-POOR BIPHENYL-TYPE LIGANDS FOR TRANSITION-METAL CATALYSTS [J].

JENDRALLA, H ;

LI, CH ;

PAULUS, E .

TETRAHEDRON-ASYMMETRY, 1994, 5 (07) :1297-1320