HETEROBINUCLEAR OXO-BRIDGED COMPLEXES .3. CR(III)OMO(V) COMPOUNDS - SYNTHESIS AND MAGNETIC-PROPERTIES

被引：6

作者：

ELLIOTT, RL

KRUGER, P

MURRAY, KS

WEST, BO

机构：

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1992年 / 45卷 / 05期

关键词：

D O I：

10.1071/CH9920889

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Redox reactions between Cr(IV)O(P) (P is a porphyrin dianion) and Mo(IV)O(dtc)2 (dtc is a dithiocarbamate anion) result in the formation of oxo-bridged Cr(III)OMo(V) compounds. The variation of magnetic susceptibility with temperature to 25 K shows evidence for strong antiferromagnetic coupling for the pyrrolidyldithiocarbamate complex with J = -300 cm-1.

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页码：889 / 896

页数：8

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