NONEXCHANGEABLE POTASSIUM ASSOCIATED WITH HYDROXY-INTERLAYERED VERMICULITE FROM COASTAL-PLAIN SOILS

被引:23
作者
HARRIS, WG [1 ]
HOLLIEN, KA [1 ]
YUAN, TL [1 ]
BATES, SR [1 ]
ACREE, WA [1 ]
机构
[1] UNIV FLORIDA,DEPT MAT ENGN,GAINESVILLE,FL 32611
关键词
Potassium Compounds--Chemical Reactions - Soils--Analysis;
D O I
10.2136/sssaj1988.03615995005200050053x
中图分类号
S15 [土壤学];
学科分类号
0903 ; 090301 ;
摘要
Hydroxy-interlayered vermiculite (HIV) from a Quartzipsamment, a Haplaquod, and a Paleudult from Florida was studied to determine levels of nonexchangeable K associated with this mineral. Results confirmed that most phyllosilicate grains from quartz- and HIV-dominted silt fractions of all samples contained sufficient K to be detected in K x-ray dot images, though little or no mica was detectable by x-ray diffractometry (XRD). High K2O values, mica-like grain morphology, and relatively large size of these grains suggest that they are transformation products of mica. Acid extracts from the clay also contained detectable levels of K. Nonexchangeable K may reside within grains as small occluded mica zones with insufficient periodicity for XRD detection, or could be retained in the 1.4-nm structure.
引用
收藏
页码:1486 / 1492
页数:7
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