STRUCTURE OF COPPER 4-(N,N-DIMETHYLAMINO)PYRIDINE COMPLEXES AND THEIR CATALYTIC ACTIVITY IN THE OXIDATIVE COUPLING OF 2,6-DIMETHYLPHENOL

被引：25

作者：

KONING, CE

CHALLA, G

HULSBERGEN, FB

REEDIJK, J

机构：

[1] STATE UNIV GRONINGEN,POLYMER CHEM LAB,NIJENBORGH 16,9747 AG GRONINGEN,NETHERLANDS

[2] STATE UNIV LEIDEN,GORLAEUS LABS,DEPT CHEM,2300 RA LEIDEN,NETHERLANDS

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1986年 / 34卷 / 03期

关键词：

CATALYSTS; -; Copper; PHENOLS; Oxidation;

D O I：

10.1016/0304-5102(86)87014-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidative coupling of 2,6-dimethylphenol (DMP) by copper complexes of 4-(N,N-dimethylamino)pyridine (DMAP) has been studied. Catalytic experiments were carried out in which the DMAP-to-copper ratio and the amount and nature of the copper counter ions were varied. Supporting UV and EPR experiments were performed, and it was concluded that both dinuclear and mononuclear complexes are catalytically active, the mononuclear species being the more active. In solution both species are in equilibrium with one another.

引用

页码：355 / 379

页数：25

共 30 条

[1] THE CRYSTAL-STRUCTURE OF CHLOROTRIS(3-METHYLPYRIDINE)COPPER(I), AND ITS CONVERSION INTO HEXA-MU-CHLORO-TETRAKIS(3-METHYLPYRIDINE)-MU-4-OXO-TETRACOPPER(II) [J].