REACTION OF DIETHYLALUMINUM CHLORIDE WITH DIAZA-18-CROWN-6 - SYNTHESIS AND MOLECULAR-STRUCTURE OF [(ETAL)2.DIAZA-18-CROWN-6]2+ - A NOVEL AZA CROWN-ETHER STABILIZED SQUARE-PYRAMIDAL COORDINATION OF ALUMINUM

被引：43

作者：

SELF, MF ^{[1
]}

PENNINGTON, WT ^{[1
]}

LASKE, JA ^{[1
]}

ROBINSON, GH ^{[1
]}

机构：

[1] CLEMSON UNIV,DEPT CHEM,CLEMSON,SC 29634

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1021/om00047a020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystalline complex [(EtAl)2.diaza-18-crown-6][EtAlCl3]2 has been prepared and its structure determined by X-ray diffraction. The [(EtAl)2.diaza-18-crown-6]2+ cation contains two five-coordinate aluminum atoms, both residing in square-pyramidal environments. The title compond appears to have resulted from an interesting disproportionation of diethylaluminum chloride.

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页码：36 / 38

页数：3

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