ETHYLENE PI-SPECIES ON BARE AND K-PRECOVERED, CS-PRECOVERED AND O-PRECOVERED PT(111) - A TDS AND UPS STUDY

被引:6
作者
CASSUTO, A
TOUFFAIRE, M
HUGENSCHMIDT, M
DOLLE, P
JUPILLE, J
机构
[1] CNRS, Laboratoire Maurice Letort, associé à l'Université de Nancy I, Route de Vandœuvre
关键词
D O I
10.1016/S0042-207X(05)80145-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
π-Bonded ethylene species are formed on bare Pt(111) at temperatures lower than 52 K and on Cs-, K- and O-precovered Pt(111) at 95 K. These new species are almost undistorted compared to gaseous ethylene, with the exception of ethylene coadsorbed with O atoms. UPS shows molecular orbital shifts in agreement with the electrostatic field existing in the vicinity of the adatoms. © 1990 Pergamon Press plc.
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页码:161 / 162
页数:2
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