A WATER-SOLUBLE POLY(METHYLPHENYLSILYLENE) DERIVATIVE AS A PHOTOINITIATOR OF RADICAL POLYMERIZATION OF HYDROPHILIC VINYL MONOMERS

被引：29

作者：

KMINEK, I

YAGCI, Y

SCHNABEL, W

机构：

[1] ISTANBUL TECH UNIV, DEPT CHEM, MASLAK 80626, TURKEY

[2] HAHN MEITNER INST KERNFORSCH BERLIN GMBH, BEREICH PHOTOCHEM ENERGIEUMWANDLUNG, W-1000 BERLIN 39, GERMANY

来源：

POLYMER BULLETIN | 1992年 / 29卷 / 3-4期

关键词：

D O I：

10.1007/BF00944819

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Radicals formed during photoscission of the pyridinium salt of partially chloromethylated poly(methylphenylsilylene) (Q-PMPSi) in aqueous solution are capable of initiating the polymerization of hydrophilic vinyl monomers, e.g. acrylic and methacrylic acid, acrylamide, 2-hydroxyethyl methacrylate and 1-vinyl-2-pyrrolidone. [GRAPHICS]

引用

页码：277 / 282

页数：6