SYNTHESIS OF SARMENTOSINE, AN AMIDE ALKALOID FROM PIPER SARMENTOSUM

被引：12

作者：

STRUNZ, GM

FINLAY, H

机构：

[1] Canadian Forest Service, Fredericton, NB E3B 5P7

来源：

PHYTOCHEMISTRY | 1995年 / 39卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

PIPER SARMENTOSUM; PIPERACEAE; SARMENTOSINE; SYNTHESIS; ALDOL; FRAGMENTATION; 2-ALKENAMIDE; BIS[N; N-BIS(TRIMETHYLSILYL)AMINO]-TIN; (II); SELENIDE; OXONE;

D O I：

10.1016/0031-9422(95)00077-K

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Sarmentosine, 7-(3',4'-methylenedioxyphenyl)-2E,6E-heptadienoic acid pyrrolidylamide, isolated from fruit of Piper sarmentosum, was synthesized in an overall yield of 21%, by a short efficient pathway in which the key step was an aldol-Grob fragmentation sequence.

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页码：731 / 733

页数：3

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