DIASTEREOSELECTIVITY OF THE CONJUGATE ADDITION OF ORGANOCOPPER REAGENTS TO (E)-GAMMA-HYDROXY-ALPHA,BETA-UNSATURATED SULFONES

被引：16

作者：

DOMINGUEZ, E ^{[1
]}

CARRETERO, JC ^{[1
]}

机构：

[1] UNIV AUTONOMA MADRID,FAC CIENCIAS,DEPT QUIM,E-28049 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 36期

关键词：

VINYL SULFONES; ORGANOCOPPER REAGENTS; STEREOSELECTIVE CONJUGATE ADDITIONS; ACYCLIC STEREOCONTROL;

D O I：

10.1016/S0040-4039(00)73865-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The conjugate addition of organocopper reagents, mainly the higher order cuprates R3CuLi2, to (E)-gamma-hydroxy-alpha,beta-unsaturated phenyl sulfones takes place with excellent yields and high anti-selectivity.

引用

页码：5803 / 5806

页数：4

共 14 条

[1] SYNTHESIS AND CONJUGATE ADDITIONS TO (E)-GAMMA-ALKOXY-ALPHA-SUBSTITUTED-ALPHA-BETA-UNSATURATED SULFONES
ALCARAZ, C
CARRETERO, JC
DOMINGUEZ, E
[J]. TETRAHEDRON LETTERS, 1991, 32 (10) : 1385 - 1388
[2] A NEW METHOD FOR THE ITERATIVE CONSTRUCTION OF ENANTIOMERICALLY PURE POLYPROPIONATE CHAINS
CARRETERO, JC
DOMINGUEZ, E
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (06) : 1596 - 1600
[3] FACILE SYNTHESIS OF E-GAMMA-HYDROXY-ALPHA,BETA-UNSATURATED SULFONES FROM ALDEHYDES
DOMINGUEZ, E
CARRETERO, JC
[J]. TETRAHEDRON LETTERS, 1990, 31 (17) : 2487 - 2490
[4] DOMINGUEZ E, 1992, J ORG CHEM, V57, P3867
[5] GUNS BW, 1993, TETRAHEDRON LETT, V34, P1417
[6] IBUKA T, 1992, SYNLETT, P769
[7] SYN-S(N)2' PATHWAY IN THE REACTION OF CERTAIN GAMMA-(MESYLOXY) ALPHA, BETA-ENOATES WITH RCU(CN)MGX.BF3 REAGENTS - IMPORTANCE OF MGX AND BULKY R-GROUP UPON THE DIASTEREOSELECTIVITY
IBUKA, T
TAGA, T
HABASHITA, H
NAKAI, K
TAMAMURA, H
FUJII, N
CHOUNAN, Y
NEMOTO, H
YAMAMOTO, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (05) : 1207 - 1214
[8] LENORD J, 1987, TETRAHEDRON LETT, V28, P2525
[9] lsobe M, 1987, STUDIES ORGANIC CHEM, V28, P209
[10] SYNTHESIS OF BETA-HYDROXY AND GAMMA-HYDROXY SULFONES BY REGIOSELECTIVE OPENING OF BETA,GAMMA-EPOXY SULFONES
NAJERA, C
SANSANO, JM
[J]. TETRAHEDRON, 1990, 46 (11) : 3993 - 4002

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