BAEYER-VILLIGER OXIDATION OF KETONES USING MOLECULAR-OXYGEN AND BENZALDEHYDE IN THE ABSENCE OF METAL-CATALYSTS

被引：87

作者：

KANEDA, K ^{[1
]}

UENO, S ^{[1
]}

IMANAKA, T ^{[1
]}

SHIMOTSUMA, E ^{[1
]}

NISHIYAMA, Y ^{[1
]}

ISHII, Y ^{[1
]}

机构：

[1] KANSAI UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 564,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 11期

关键词：

D O I：

10.1021/jo00090a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A combination system of molecular oxygen, benzaldehyde, and carbon tetrachloride oxidizes various ketones to give lactones and esters in high yields at 40 degrees C, and addition of benzoyl chloride increases yields of the Baeyer-Villiger oxidation products at a lower temperature of 20 degrees C.

引用

页码：2915 / 2917

页数：3

共 17 条

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