A ONE-STEP SYNTHESIS OF ALKENYLIDENE, DIENYLIDENE AND TRIENYLIDENE COMPLEXES OF CHROMIUM AND TUNGSTEN CARBONYL

被引：15

作者：

LEBOZEC, H

COSSET, C

DIXNEUF, PH

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 13期

关键词：

D O I：

10.1039/c39910000881

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkenyl-, dienyl- and trienylidene-chromium and tungsten complexes (CO)5M = [C(OMe){CH = CH-(CH = CH)n-R}] [n = 0, 1,2] are produced in one step by photolysis of M(CO)6 [M = Cr, W] in the presence of 2-propyn-1-ol derivatives H-C = CC(H)(OH)[CH = CH)n-R] and methanol.

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页码：881 / 882

页数：2

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