SELECTIVE REDUCTION OF CONJUGATED DOUBLE-BONDS WITH MOLECULAR-HYDROGEN AND PALLADIUM(II) COMPLEXED TO FERROCENYLAMINE SULFIDE CATALYSTS

被引：9

作者：

ALI, HM ^{[1
]}

NAIINI, AA ^{[1
]}

BRUBAKER, CH ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

关键词：

D O I：

10.1016/0040-4039(91)80065-E

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly catalytic chemo- and regioselectivity have been achieved for the reduction of carbon-carbon double bonds conjugated to different unsaturated functional groups by molecular hydrogen and palladium(II) complexes of ferrocenylamine sulfides. Chemical yields and selectivities were more than 99% in many cases.

引用

页码：5489 / 5492

页数：4

共 19 条

[1]

ALI HM, IN PRESS J MOL CATAL

[2] ACTIVATION OF REDUCING AGENTS - SODIUM HYDRIDE CONTAINING COMPLEX REDUCING AGENTS .27. REDUCTION OF ETHYLENIC INSATURATIONS BY INSITU GENERATED HYDROGEN [J].