FT-IR SPECTROSCOPY, A MAJOR TOOL FOR THE ANALYSIS OF PEROXIDE VULCANIZATION PROCESSES IN THE PRESENCE OF COAGENTS .1. MECHANISM OF EPM PEROXIDE VULCANIZATION WITH AROMATIC BIS(ALLYL)ESTERS AS COAGENTS

被引：37

作者：

DIKLAND, HG ^{[1
]}

VANDERDOES, L ^{[1
]}

BANTJES, A ^{[1
]}

机构：

[1] UNIV TWENTE,DEPT CHEM TECHNOL,POLYMER MAT SECT,7500 AE ENSCHEDE,NETHERLANDS

来源：

RUBBER CHEMISTRY AND TECHNOLOGY | 1993年 / 66卷 / 02期

关键词：

D O I：

10.5254/1.3538306

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this paper the results of investigations on the mechanism of EPM peroxide vulcanizations in the presence of various bis(allyl)esters of aromatic diacids-as coagents-are presented. These coagents are commonly used in the rubber industry to increase the crosslinking efficiency, however, until now the mechanism of this process remained unclear. In our studies it is demonstrated that when using FT-IR spectroscopy in combination with equilibrium swelling techniques and atomic force scanning microscopy, the role of the coagents can be elucidated.

引用

页码：196 / 212

页数：17

共 37 条

[1] CURING OF FLUOROELASTOMERS BY PEROXIDES [J].

APOTHEKER, D ;

FINLAY, JB ;

KRUSIC, PJ ;

LOGOTHETIS, AL .

RUBBER CHEMISTRY AND TECHNOLOGY, 1982, 55 (04) :1004-1018

[2]

BALDWIN FP, 1970, RUBBER CHEM TECHNOL, V43, P1167

[3]

Cornell J. A., 1970, RUBBER CHEM TECHNOL, V43, P613

[4] ANALYSIS OF CURING KINETICS IN POLYMER COMPOSITES [J].

CRANE, LW ;

DYNES, PJ ;

KAELBLE, DH .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1973, 11 (08) :533-540

[5]

DAKIN VI, 1977, INT POLYM SCI TECHN, V4, pT34

[6]

DIKLAND HG, IN PRESS POLYM COMMU

[7]

DIKLAND HG, IN PRESS

[8]

DONTSOV AA, 1978, POLYM SCI USSR A, V20, P113

[9]

Dusek K, 1969, ADV POLYM SCI, V6, P1

[10]

ENDSTRA WC, 1991, APR P INT C LEUV

← 1 2 3 4 →