LANTHANIDE TRIFLUOROMETHANESULFONATES AS STABLE LEWIS-ACIDS IN AQUEOUS-MEDIA - YB(OTF)3 CATALYZED HYDROXYMETHYLATION REACTION OF SILYL ENOL ETHERS WITH COMMERCIAL FORMALDEHYDE SOLUTION

被引：204

作者：

KOBAYASHI, S

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 12期

关键词：

D O I：

10.1246/cl.1991.2187

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Silyl enol ethers smoothly react with commercial formaldehyde solution to give the corresponding hydroxymethylated adducts in high yields by the promotion of a catalytic amount of ytterbium(III) triflate (Yb(OTf)3), which is a stable Lewis acid in aqueous media. Other lanthanide triflates are also found to be effective.

引用

页码：2187 / 2190

页数：4

共 34 条

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