AN EXAMINATION OF THE VAPOR-LIQUID-EQUILIBRIUM IN THE SYSTEM PROPANE HYDROGEN-SULFIDE

被引:10
作者
CARROLL, JJ [1 ]
MATHER, AE [1 ]
机构
[1] UNIV ALBERTA,DEPT CHEM ENGN,EDMONTON T6G 2G6,ALBERTA,CANADA
关键词
D O I
10.1016/0378-3812(92)85151-W
中图分类号
O414.1 [热力学];
学科分类号
摘要
A review of the literature for the system propane-hydrogen sulfide revealed significant discrepancies between the various experimental investigations. This is particularly true for the location of the azeotrope. This paper investigates the problems with the experimental data for this system. Each investigation is reviewed in detail to determine sources of error. The Peng-Robinson equation of state is used as a tool for this interpretation. What is revealed is a clearer picture of the phase equilibrium that is consistent with the data of the major investigations of this system.
引用
收藏
页码:187 / 204
页数:18
相关论文
共 11 条
[1]  
[Anonymous], 1987, PROPERTIES GASES LIQ
[2]   PHASE EQUILIBRIA OF THE PROPANE-HYDROGEN SULFIDE SYSTEM FROM THE CRICONDONTHERM TO THE SOLID-LIQUID-VAPOR REGION [J].
BREWER, J ;
RODEWALD, N ;
KURATA, F .
AICHE JOURNAL, 1961, 7 (01) :13-16
[3]  
BREWER J, 1960, THESIS U KANSAS LAWR
[4]   P-V-T relations for propane [J].
Deschner, WW ;
Brown, GG .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1940, 32 :836-840
[5]   High-pressure vapor-liquid equilibrium - For the systems propylene-isobutane and propane-hydrogen sulfide [J].
Gilliland, ER ;
Scheeline, HW .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1940, 32 :48-54
[6]  
Goodwin R. D., 1983, NBSIR831694
[7]   LIQUID-VAPOR EQUILIBRIUM RELATIONS IN BINARY SYSTEMS - PROPANE-HYDROGEN SULFIDE SYSTEM [J].
KAY, WB ;
RAMBOSEK, GM .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1953, 45 (01) :221-226
[8]  
KNAPP H., 1982, VAPOR LIQUID EQUILIB, VVI
[10]   A New Two-Constant Equation of State [J].
PENG, D ;
ROBINSON, DB .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1976, 15 (01) :59-64