STRUCTURAL STUDIES ON OXALATOTRIORGANOSTANNATES - CRYSTAL-STRUCTURE OF TRIMETHYLSULFONIUM CATENA-O, O'-OXALATOTRIPHENYLSTANNATE

被引：8

作者：

NG, SW ^{[1
]}

DAS, VGK ^{[1
]}

LUO, BS ^{[1
]}

MAK, TCW ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1994年 / 209卷 / 11期

关键词：

CRYSTAL STRUCTURE;

D O I：

10.1524/zkri.1994.209.11.882

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of trimethylsulfonium oxalatotriphenylstannate, C23H24O4SSn, synthesized from the metathetical reaction of trimethylsulfonium iodide, silver oxalate and triphenyltin chloride in methanol, consists of [(CH3)3S]+ ions interspersed among the linear [(C6H5)3SnO2CCO2]n(n-) chains that are constructed from [O2CCO2]2- dianions bonded axially to planar [(C6H5)3Sn]+ (Sn - O = 2.220(3) angstrom, SIGMA C - Sn - C = 360.0(4)-degrees) cations.

引用

页码：882 / 884

页数：3

共 9 条

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