UNSATURATED NITROGEN-COMPOUNDS CONTAINING FLUORINE .7. THE REACTION OF 2,5-DICHLORO-1,1,1,6,6,6-HEXAFLUORO-3,4-DIAZAHEXA-2,4-DIENE WITH PHENYL-LITHIUM

被引：7

作者：

BENOMAR, S ^{[1
]}

PATEL, B ^{[1
]}

TIPPING, AE ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 50卷 / 02期

关键词：

D O I：

10.1016/S0022-1139(00)80496-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the title azine (1) with phenyl-lithium results in initial replacement of chlorine by phenyl to give the monophenylazine (4) and then the diphenylazine (5), but this is followed by successive replacement of fluorine in one CF3 group to afford first the 3,4-diazahexa-1,3-diene CF3CPh2NNCPhCXY (6) (XYF), then (7) (XF,YPh) and finally (8) (XYPh). © 1990.

引用

页码：207 / 215

页数：9

共 5 条

[1] UNSATURATED NITROGEN-COMPOUNDS CONTAINING FLUORINE .6. REACTIONS OF HEXAFLUOROACETONE AZINE WITH 2-METHYLBUT-2-ENE, 2,3-DIMETHYL-BUT-2-ENE, 2,3-DIMETHYLBUT-1-ENE, AND CYCLOPENTENE [J].

ARMSTRONG, SE ;

FORSHAW, TP ;

TIPPING, AE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (19) :1902-1907

[2] THE PREPARATION AND SOME REACTIONS OF 2,5-DICHLORO-1,1,1,6,6,6-HEXAFLUORO-3,4-DIAZAHEXA-2,4-DIENE [J].

BARLOW, MG ;

BELL, D ;

OREILLY, NJ ;

TIPPING, AE .

JOURNAL OF FLUORINE CHEMISTRY, 1983, 23 (03) :293-299

[3]

BENOMAR S, IN PRESS ACTA CRYST

[4]

OREILLY NJ, 1984, THESIS MANCHESTER

[5]

PATEL B, 1988, UNPUB

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