BIS(ETA-CYCLOPENTADIENYL)IMIDOMOLYBDENUM COMPOUNDS

被引：19

作者：

GREEN, MLH

KONIDARIS, PC

MICHAELIDOU, DM

MOUNTFORD, P

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 02期

关键词：

D O I：

10.1039/dt9950000155

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mono(eta-cyclopentadienyl)imide compounds [Mo(eta-C(5)H(6)R)(NR')Cl-2] (R, R' = H, R''; Me, Pr-i; Me, R''; or Pr-i, R''; R'' = C(6)H(3)Me(2)-2,6) and the new bis(eta-cyclopentadienyl)imide compounds [Mo(eta-C(5)H(4)R)(2)(NR')] (R, R' = Me. Bu(t); H. Bu(t); H. Pr-i; H. Ph; H, R''; Me. Pr-i; Me, Ph; Me, R''; Pr-i, Bu(t); or Pr-i, R''), [Mo(eta-C5H5)(eta-C5H4Pri)(NBUt)], [Mo(eta(3)-C9H7) (eta-C5H4Pri)(NBu(t))] and [Mo(eta-C(5)H(4)Me)(2)- Me(NBu(t))]X (X = 1 or B F-4) have been prepared. The salt [Mo(eta-C(5)H(4)Me) (PMe(3))(2)(NBu(t))l [C(5)H(4)Me] has also been prepared. The crystal structures of the latter and of [Mo(eta-C5H5)(2)(NBu(t))] have been determined.

引用

页码：155 / 162

页数：8

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[2]

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