TIME-RESOLVED INFRARED SPECTROSCOPIC DIAGNOSIS OF A BIMOLECULAR CHEMICAL-REACTION IN ROOM-TEMPERATURE SOLUTION - THE CCL3 RADICAL PRODUCED FROM PHOTOEXCITED TRANS-STILBENE AND CARBON-TETRACHLORIDE

被引：6

作者：

IWATA, K

KATAOKA, S

HAMAGUCHI, H

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2131

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The newly found photochemical reaction between trans-stilbene and carbon tetrachloride was examined with time-resolved infrared spectroscopy. On the photoexcitation of trans-stilbene in a carbon tetrachloride solution at room temperature, an intense infrared band was observed at 896 cm(-1). This band is identified as a band the trichloromethyl (CCl3) radical. It has been clarified that photoexcited trans-stilbene abstracts hydrogen from carbon tetrachloride to generate the CCl3 radical.

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页码：2131 / 2134

页数：4

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