CATALYTIC HALOGENATION OF SELECTED ORGANIC-COMPOUNDS MIMICKING VANADATE-DEPENDENT MARINE METALLOENZYMES

被引:44
作者
DINESH, CU [1 ]
KUMAR, R [1 ]
PANDEY, B [1 ]
KUMAR, P [1 ]
机构
[1] NATL CHEM LAB,DIV ORGAN CHEM TECHNOL,POONA 411008,MAHARASHTRA,INDIA
关键词
D O I
10.1039/c39950000611
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ammonium metavanadate, mimicking vanadate-dependent metalloenzymes, efficiently catalyses the halogenation of a variety of organic substrates in dilute conditions in moderate to good yields using dilute hydrogen peroxide (30%) as an oxidizing agent exhibiting remarkable ortho selectivity with electron-rich aromatics.
引用
收藏
页码:611 / 612
页数:2
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