INTERPRETATION OF THE ABSORPTION-SPECTRUM OF NA8

被引：58

作者：

BONACICKOUTECKY, V

KAPPES, MM

FANTUCCI, P

KOUTECKY, J

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

[2] UNIV MILAN,CNR,DIPARTIMENTO CHIM INORGAN & MET ORGAN,I-20133 MILAN,ITALY

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 170卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(90)87084-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The optically allowed transitions for three neutral Na8 structures (Td, D2d and D4d) and their oscillator strength have been determined using the configuration-interaction procedure. The assignment to the observed optical response spectrum exhibiting a very intense transition at 494 nm and fine structure at ≈ 590 and ≈ 730 nm has been made using the calculated spectrum of the Td and related D2d structures. The antiprism form of Na8 yields blue-shifted transitions with respect to the observed ones. The quantum-molecular approach has been compared with the semiclassical Mie-Drude model. © 1990.

引用

页码：26 / 34

页数：9

共 33 条

[1] Bashkin S., 1975, ATOMIC ENERGY LEVELS
[2] SYSTEMATIC ABINITIO CONFIGURATION-INTERACTION STUDY OF ALKALI-METAL CLUSTERS .2. RELATION BETWEEN ELECTRONIC-STRUCTURE AND GEOMETRY OF SMALL SODIUM CLUSTERS
BONACICKOUTECKY, V
FANTUCCI, P
KOUTECKY, J
[J]. PHYSICAL REVIEW B, 1988, 37 (09): : 4369 - 4374
[3] AN ABINITIO CONFIGURATION-INTERACTION STUDY OF THE EXCITED-STATES OF THE NA4 CLUSTER - ASSIGNMENT OF THE ABSORPTION-SPECTRUM
BONACICKOUTECKY, V
FANTUCCI, P
KOUTECKY, J
[J]. CHEMICAL PHYSICS LETTERS, 1990, 166 (01) : 32 - 38
[4] AN ABINITIO CONFIGURATION-INTERACTION INVESTIGATION OF THE EXCITED-STATES OF THE LI4 CLUSTER
BONACICKOUTECKY, V
FANTUCCI, P
KOUTECKY, J
[J]. CHEMICAL PHYSICS LETTERS, 1988, 146 (06) : 518 - 523
[5] ABINITIO CONFIGURATION-INTERACTION STUDY OF THE ELECTRONIC AND GEOMETRIC STRUCTURES OF SMALL SODIUM CATIONIC CLUSTERS
BONACICKOUTECKY, V
BOUSTANI, I
GUEST, M
KOUTECKY, J
[J]. JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (08) : 4861 - 4866
[6] BONACICKOUTECKY V, UNPUB
[7] BONACICKOUTECKY V, IN PRESS
[8] COLLECTIVE EXCITATION IN CLOSED-SHELL POTASSIUM CLUSTER IONS
BRECHIGNAC, C
CAHUZAC, P
CARLIER, F
LEYGNIER, J
[J]. CHEMICAL PHYSICS LETTERS, 1989, 164 (04) : 433 - 437
[9] SIZE-SELECTIVE DEPLETION SPECTROSCOPY OF PREDISSOCIATED STATES OF NA-3
BROYER, M
DELACRETAZ, G
LABASTIE, P
WOLF, JP
WOSTE, L
[J]. PHYSICAL REVIEW LETTERS, 1986, 57 (15) : 1851 - 1854
[10] BROYER M, UNPUB

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