SYNTHESIS AND CHARACTERIZATION OF METAL DERIVATIVES OF DIHYDROLIPOIC ACID AND DIHYDROLIPOAMIDE

被引：16

作者：

BONOMI, F

PAGANI, S

CARIATI, F

POZZI, A

CRISPONI, G

CRISTIANI, F

DIAZ, A

ZANONI, R

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM INORGAN & MET ORGAN,VIA VENEZIAN 21,I-20133 MILAN,ITALY

[2] UNIV MILAN,DIPARTIMENTO SCI MOLEC AGROALIMENTARI,I-20133 MILAN,ITALY

[3] UNIV CAGLIARI,DIPARTIMENTO CHIM & TECNOL INORGAN & MET ORGAN,I-09124 CAGLIARI,ITALY

[4] UNIV LA SAPIENZA,DIPARTIMENTO CHIM,I-00100 ROME,ITALY

来源：

INORGANICA CHIMICA ACTA | 1992年 / 192卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)80765-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes formed by the dianions LH2- and L'2- deriving from dihydrolipoic acid (LH3) and dihydrolipoamide (L'H2), respectively, by substitution of the hydrogen atoms of the thiol groups with Ni(II), Co(II), Hg(II) and Cu(I) ions were synthesized, isolated and characterized. In all these compounds the metal ions are coordinated to the thiolic sulfur atoms of the ligands. Potentiometric and spectroscopic data (IR, UV-Vis, EPR and XPS) obtained for these complexes or for their solutions are discussed.

引用

页码：237 / 242

页数：6

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