CONJUGATE REDUCTION OF QUINONE DERIVATIVES - A ROUTE TO PHENOL KETO-TAUTOMER EQUIVALENTS

被引：13

作者：

DOTY, BJ ^{[1
]}

MORROW, GW ^{[1
]}

机构：

[1] UNIV DAYTON, DEPT CHEM, DAYTON, OH 45469 USA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)97004-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,4-addition of hydride to quinone monoketals 1 and p-quinol ethers 2, mediated by bis-(2,6-di-t-butyl-4-methylphenoxy)-methylaluminum (MAD), affords 4,4-substituted-2-cyclohexen-1-ones 3, which represent keto-tautomer equivalents of phenols. © 1990.

引用

页码：6125 / 6128

页数：4

共 10 条

[1]

HENTON DR, 1980, J ORG CHEM, V45, P3422, DOI 10.1021/jo01305a010

[2]

KOENIG TM, 1990, TETRAHEDRON LETT, P3237

[3]

LIPSHUTZ BH, 1989, SYNLETT, V1, P64

[4] AMPHIPHILIC REACTIONS BY MEANS OF EXCEPTIONALLY BULKY ORGANO-ALUMINUM REAGENTS - RATIONAL APPROACH FOR OBTAINING UNUSUAL EQUATORIAL, ANTI-CRAM, AND 1,4 SELECTIVITY IN CARBONYL ALKYLATION [J].