ADDUCT INFLUENCES ON (CYCLOPENTADIENYL)LITHIUM

被引：15

作者：

BLOM, R ^{[1
]}

FAEGRI, K ^{[1
]}

MIDTGAARD, T ^{[1
]}

机构：

[1] UNIV OSLO,DEPT CHEM,POB 1033,N-0315 OSLO 3,NORWAY

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 09期

关键词：

D O I：

10.1021/ja00009a003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Extensive SCF calculations have been carried out to determine the metal-ring distance in compounds derived from (cyclopentadienyl)lithium by the addition of N-containing ligands coordinated to the Li atom. NH3 groups have been used to model the ligands. The calculations suggest that the compounds are largely ionic with the N lone pairs coordinating to the positive Li atom, leading to longer and weaker metal-ring bonds. The effect of correlation is discussed on the basis of MP2 calculations for the smaller systems.

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页码：3230 / 3235

页数：6

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