PYRYLIUM-SALTS .7. 2,4,6-TRIPHENYL-PYRYLIUM TRICHLOROACETATE

被引:5
作者
ANULEWICZ, R [1 ]
SWIRSKA, B [1 ]
MILART, P [1 ]
机构
[1] JAGIELLONIAN UNIV,DEPT CHEM,PL-30060 KRAKOW,POLAND
关键词
D O I
10.1107/S0108270194012515
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of C23H17O+.C2Cl3O2- has been determined. The three benzene rings are planar, but tilt from the plane of the pyrylium ring at angles of 14.9, 23.7 and 6.1 degrees, respectively. The C-C bond length in the anion is much longer than expected [1.579(7)Angstrom]. The aromatic character of the pyrylium ring is discussed.
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页码:1180 / 1182
页数:3
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