THE EFFECT OF ORTHO METHYL-GROUPS ON CUMYL SYSTEMS

被引：9

作者：

EVILIA, RF ^{[1
]}

PAN, D ^{[1
]}

TIMBERLAKE, JW ^{[1
]}

WHITTENBURG, SL ^{[1
]}

机构：

[1] UNIV NEW ORLEANS,DEPT CHEM,NEW ORLEANS,LA 70148

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(00)92108-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of 2-mesityl-2-propanol (2) and 2-mesityl-l-propene (6) have been investigated with the objective of evaluating the effect of ortho methyl groups on chemical reactivity. The C-13 NMR spectrum of 2-mesityl-2-propyl cation (3) indicates the expected steric inhibition to resonance.

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页码：871 / 874

页数：4

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