SECONDARY MOLD METABOLITES .13. FUNGAL PERYLENEQUINONES - PHLEICHROME, ISOPHLEICHROME, AND THEIR ENDOPEROXIDES

被引：35

作者：

ARNONE, A ^{[1
]}

CAMARDA, L ^{[1
]}

NASINI, G ^{[1
]}

MERLINI, L ^{[1
]}

机构：

[1] UNIV MILAN, FAC AGR, IST BIOCHIM GEN, I-20133 MILAN, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1985年 / 07期

关键词：

D O I：

10.1039/p19850001387

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The helix-shaped, fungal [Cladosporium phlei] pigment phleichrome has been isomerized to isophleichrome. The axial chirality and absolute configuration of the side-chain carbons of both perylenequinones have been established. Photo-oxidation of both compounds occurs stereospecifically to give their endoperoxides, whose structure and stereochemistry results from a detailed analysis of their n.m.r. spectra.

引用

页码：1387 / 1392

页数：6

共 15 条

[1] ARNONE A, UNPUB
[2] ASSANTE G, PHYTOPATHOL MEDITERR
[3] CHEMISTRY OF SINGLET OXYGEN .46. CERCOSPORIN, A SINGLET OXYGEN GENERATOR
DOBROWOLSKI, DC
FOOTE, CS
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (09): : 720 - 721
[4] Gollnick K., 1967, Organic Chemistry, P255
[5] Horeau A., 1977, Stereochemistry: Fundamentals andMethods, V3, P51
[6] PIGMENTS OF ELSINOE SPECIES .3. METHYLATION OF ELSINOCHROME-A - FORMATION OF MONO-METHYL AND DI-METHYL ETHERS
LOUSBERG, RJ
WEISS, U
SALEMINK, CA
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1970, (16): : 2152 - &
[7] LOUSBERG RJJ, 1971, CHEM COMMUN, P1463
[8] MERLINI L, 1984, CHEM BIOTECHNOLOGY B, P121
[9] MINO Y, 1979, Annals of the Phytopathological Society of Japan, V45, P463, DOI 10.3186/jjphytopath.45.463
[10] SECONDARY MOLD METABOLITES .12. STEREOCHEMISTRY OF CERCOSPORIN
NASINI, G
MERLINI, L
ANDREETTI, GD
BOCELLI, G
SGARABOTTO, P
[J]. TETRAHEDRON, 1982, 38 (18) : 2787 - 2796

← 1 2 →