TRIALKYLTIN CATION IN SOLUTION

被引：18

作者：

KIRA, M

OYAMADA, T

SAKURAI, H

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Aoba-ku, Sendai

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 471卷 / 1-2期

关键词：

TIN; BORATE; CATION; GROUP-14;

D O I：

10.1016/0022-328X(94)88137-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Definitive evidence for the formation of a long-lived trivalent tin cation was obtained by using a well-defined reaction, i.e. the abstraction of hydride from tributyltin by trityl tetrakis[3,5-bis(trifluoromethyl) phenyl]borate in dichloromethane-d2. The Sn-119 resonance at around 360 ppm is indicative of no significant interaction between the tin cation and the counteranion.

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页码：C4 / C5

页数：2

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