A NOVEL RECEPTOR FOR DICARBOXYLIC-ACID DERIVATIVES

被引：49

作者：

FLACK, SS ^{[1
]}

CHAUMETTE, JL ^{[1
]}

KILBURN, JD ^{[1
]}

LANGLEY, GJ ^{[1
]}

WEBSTER, M ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期

关键词：

D O I：

10.1039/c39930000399

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel receptor 4 has been prepared, which binds the monopotassium salts of various dicarboxylic acids in chloroform solution, using a combination of hydrogen bonding interactions and an electrostatic association between a carboxylate anion and a crown ether bound potassium cation, the crystal structure of the receptor is reported and evidence for the proposed binding interactions is provided by consideration of various extraction experiments, intermolecular NOEs (nuclear Overhausser effect), and FAB (fast atom bombardment) mass spectrometry, where a bimolecular species, held together by hydrogen bonds, can be detected in the negative ion mass spectrum.

引用

页码：399 / 401

页数：3

共 14 条

[1] ALBERT J, 1991, J CHEM SOC CHEM COMM, P1761
[2] MOLECULAR RECOGNITION .2. MOLECULAR RECOGNITION OF AMINO-ACIDS - 2-POINT FIXATION OF AMINO-ACIDS WITH BIFUNCTIONAL METALLOPORPHYRIN RECEPTORS
AOYAMA, Y
YAMAGISHI, A
ASAGAWA, M
TOI, H
OGOSHI, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (12) : 4076 - 4077
[3] STRUCTURE DETERMINATION OF A TETRASACCHARIDE - TRANSIENT NUCLEAR OVERHAUSER EFFECTS IN THE ROTATING FRAME
BOTHNERBY, AA
STEPHENS, RL
LEE, JM
WARREN, CD
JEANLOZ, RW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) : 811 - 813
[4] MOLECULAR COMPLEXATION - BETA-CYCLODEXTRIN AND BENZALDEHYDE INCLUSION COMPLEX
CHOI, HS
KNEVEL, AM
CHANG, CJ
[J]. PHARMACEUTICAL RESEARCH, 1992, 9 (05) : 690 - 693
[5] A RECEPTOR FOR THE ENANTIOSELECTIVE RECOGNITION OF PHENYLALANINE AND TRYPTOPHAN UNDER NEUTRAL CONDITIONS
GALAN, A
ANDREU, D
ECHAVARREN, AM
PRADOS, P
DEMENDOZA, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (04) : 1511 - 1512
[6] MOLECULAR RECOGNITION - A REMARKABLY SIMPLE RECEPTOR FOR THE SELECTIVE COMPLEXATION OF DICARBOXYLIC-ACIDS
GARCIATELLADO, F
GOSWAMI, S
CHANG, SK
GEIB, SJ
HAMILTON, AD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (20) : 7393 - 7394
[7] GATTO VJ, 1990, ORG SYNTH, V68, P227
[8] HIGHLY SELECTIVE BINDING OF SIMPLE PEPTIDES BY A C3 MACROTRICYCLIC RECEPTOR
HONG, JI
NAMGOONG, SK
BERNARDI, A
STILL, WC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) : 5111 - 5112
[9] THERMODYNAMIC AND KINETIC DATA FOR MACROCYCLE INTERACTION WITH CATIONS AND ANIONS
IZATT, RM
PAWLAK, K
BRADSHAW, JS
BRUENING, RL
[J]. CHEMICAL REVIEWS, 1991, 91 (08) : 1721 - 2085
[10] MACROCYCLIC LIGANDS EXAMINED BY FAST ATOM BOMBARDMENT MASS-SPECTROMETRY - DIRECT OBSERVATION OF METAL CATION SELECTIVITY IN COMPLEXATION
JOHNSTONE, RAW
ROSE, ME
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (21) : 1268 - 1270

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