ANODIC-OXIDATION OF PROPYLENE CARBONATE AND ETHYLENE CARBONATE ON GRAPHITE-ELECTRODES

被引：85

作者：

ARAKAWA, M

YAMAKI, J

机构：

[1] Nippon Telegraph and Telephone Corporation, NTT Interdisciplinary Research Laboratories, Musashino-shi, Tokyo, 180

[2] Ibaraki-ken, 319-11, 162 Shirakata, Tokai-mura

来源：

JOURNAL OF POWER SOURCES | 1995年 / 54卷 / 02期

关键词：

PROPYLENE CARBONATE; ETHYLENE CARBONATE; GRAPHITE ELECTRODES; ANODIC OXIDATION;

D O I：

10.1016/0378-7753(94)02078-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical oxidation of electrolytes becomes a more serious problem in high voltage lithium cells. In this paper, the reaction mechanisms of propylene carbonate (PC) and ethylene carbonate (EC) are investigated by using in situ mass spectrometry and gas chromatography-mass spectrometry. When PC is oxidized, it decomposes into carbon dioxide and propylene oxide, which in turn react to form other by-products, such as propanal and 2-ethyl-4-methyl-1,3-dioxolane. Carbon dioxide is generated during EC oxidation.

引用

页码：250 / 254

页数：5

共 11 条

[1] ABRAHAM KM, 1983, LITHIUM BATTERIES, P371
[2] ANODIC STABILITY OF PROPYLENE CARBONATE ELECTROLYTES AT POTENTIALS ABOVE 4V AGAINST LITHIUM - AN ONLINE MS AND INSITU FTIR STUDY
CATTANEO, E
RASCH, B
VIELSTICH, W
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1991, 21 (10) : 885 - 894
[3] ELECTROCHEMICAL REACTIONS OF PROPYLENECARBONATE AND ELECTROLYTES SOLVED THEREIN - A DEMS STUDY
EGGERT, G
HEITBAUM, J
[J]. ELECTROCHIMICA ACTA, 1986, 31 (11) : 1443 - 1448
[4] Glugla P. G., 1980, P S POWER SOURCES BI, P407
[5] LI METAL-FREE RECHARGEABLE LIMN2O4/CARBON CELLS - THEIR UNDERSTANDING AND OPTIMIZATION
GUYOMARD, D
TARASCON, JM
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (04) : 937 - 948
[6] SUBSTITUTED 4-METHYL-1,3-DIOXOLANES - SOLVENT INTERACTION PRODUCTS IN SOME COMMERCIAL BEEF FLAVORINGS
MACLEOD, G
SEYYEDAINARDEBILI, M
MACLEOD, AJ
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1980, 28 (02) : 441 - 446
[7] DETECTION OF ELECTROLYTICALLY GENERATED TRANSIENT FREE RADICALS BY ELECTRON SPIN RESONANCE
MAKI, AH
GESKE, DH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1959, 30 (05) : 1356 - 1357
[8] ANODIC-OXIDATION OF PROPYLENE CARBONATE ON PLATINUM, GLASSY-CARBON AND POLYPYRROLE - AN INSITU FTIR STUDY
NOVAK, P
CHRISTENSEN, PA
IWASITA, T
VIELSTICH, W
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 263 (01): : 37 - 48
[9] OXIDATION POTENTIALS OF ELECTROLYTE-SOLUTIONS FOR LITHIUM CELLS
OSSOLA, F
PISTOIA, G
SEEBER, R
UGO, P
[J]. ELECTROCHIMICA ACTA, 1988, 33 (01) : 47 - 50
[10] PEPPEL WJ, 1958, IND ENG CHEM, V50, P768

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