STRUCTURE OF SURFACE SPECIES IN MO/AL2O3 CATALYSTS PREPARED THROUGH MO(V) OXALATE

被引:6
作者
STARTSEV, AN
KLIMOV, OV
SHKUROPAT, SA
KOLOSOV, PE
FEDOROV, VK
DEGTYAREV, SP
KOCHUBEI, DI
机构
[1] Institute of Catalysis, Novosibirsk
来源
REACTION KINETICS AND CATALYSIS LETTERS | 1990年 / 41卷 / 02期
关键词
D O I
10.1007/BF02097891
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
EXAFS and RED structural studies of surface species of Mo/Al2O3 catalysts prepared through the anchoring of [Mo2O4(C2O4)2(H2O)]2- anion to γ-Al2O3 have shown that these surface metal complexes preserve a binuclear structure of the Mo(V) oxalate framework fragment. © 1990 Akadémiai Kiadó.
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页码:339 / 344
页数:6
相关论文
共 8 条
[1]  
Startsev A.N., Klimov O.V., Shkuropat S.A., React. Kinet. Catal. Lett., 41, (1990)
[2]  
Klimov O.V., Startsev A.N., React. Kinet. Catal. Lett., 41, (1990)
[3]  
Chakravorti M.C., Bandyopadhyoa D., Synth. React. Inorg. Metal-Org. Chem., 14, (1984)
[4]  
Kochubei D.I., Babanov, Zamaraev K.I., Vedrinskii R.V., Kreisman V.L., Kulipanov G.N., Masalov L.N., Skirinskii A.N., Fedorov V.K., Helmer, Shuvaev A.T., ESCA Structural Studies of Amorphous Bodies, (1988)
[5]  
McKale A.G., J. Am. Chem. Soc., 110, (1988)
[6]  
Konnert J.H., Karle J., The computation of radial distribution functions for glassy materials, Acta Crystallographica Section A, 29, (1973)
[7]  
Cotton F.A., Morehouse S.M., Inorg. Chem., 4, (1965)
[8]  
Porai-Koshits M.A., Atovmyan L.O., Crystallochemistry and Stereochemistry of Coordinated Molybdenum Compounds, (1974)