PHOTOCHEMICAL RING-OPENING OF CYCLOPROPYL KETONES INDUCED BY ELECTRON-TRANSFER

被引：16

作者：

COSSY, J

FURET, N

机构：

[1] Laboratoire de Chimie Organique, Associé au C.N.R.S, E.S.P.C.I., 75231 Paris Cédex 05

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 50期

关键词：

CYCLOPROPYLKETONES; PHOTOREDUCTION; TRIETHYLAMINE; LITHIUM PERCHLORATE; RADICAL; RING ENLARGEMENT;

D O I：

10.1016/S0040-4039(00)61464-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Irradiation of substituted bicyclo[n.1.0.]alkan-2-ones at 254 nm in the presence of triethylamine and lithium perchlorate (LIClO(4)) can lead to cyclopropane ring opening with cleavage of the C(1)-C(n+2) (ring enlargement) or C(1)-C(n+3) bonds.

引用

页码：8107 / 8110

页数：4

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