CATALYTIC RING-CLOSING METATHESIS - A NEW, POWERFUL TECHNIQUE FOR CARBON-CARBON COUPLING IN ORGANIC-SYNTHESIS

被引：289

作者：

SCHMALZ, HG

机构：

[1] Institut für Organische Chemie der Technischen Universität, Berlin, D-10623

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 17期

关键词：

ALKYLIDENE COMPLEXES; CATALYSIS; CYCLIZATIONS; FLUVIRUCIN; METATHESIS REACTIONS;

D O I：

10.1002/anie.199518331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A classic reaction in organometallic chemistry has been rediscovered for organic synthesis—olefin metathesis. In this highlight methodological studies and the more recent impressive synthetic applications are described. The total synthesis of fluvirucin B1 aglycon (1) by A. H. Hoveyda is one of the latest impressive achievements. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1833 / 1836

页数：4

共 42 条

[1] NEW SYNTHESIS OF 3-CYCLOPENTENECARBOXYLIC ACID-ESTERS BY OLEFIN METATHESIS [J].

BESPALOVA, NB ;

BOVINA, MA ;

SERGEEVA, MB ;

ZAIKIN, VG .

RUSSIAN CHEMICAL BULLETIN, 1994, 43 (08) :1425-1426

[2] THE FIRST SYNTHESIS OF THE ABCD RING-SYSTEM OF MANZAMINE-A - CONSTRUCTION OF THE MACROCYCLIC RING-D [J].

BORER, BC ;

DEERENBERG, S ;

BIERAUGEL, H ;

PANDIT, UK .

TETRAHEDRON LETTERS, 1994, 35 (19) :3191-3194

[3]

BORER BC, 1994, PURE APPL CHEM, V66, P2131

[4]

BRUNNELLE DJ, 1993, RING OPENING POLYM M

[5] ACRYLONITRILE CROSS-METATHESIS - COAXING OLEFIN METATHESIS REACTIVITY FROM A RELUCTANT SUBSTRATE [J].

CROWE, WE ;

GOLDBERG, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (18) :5162-5163

[6] SOLVENT-FREE CYCLIZATION OF LINEAR DIENES USING OLEFIN METATHESIS AND THE THORPE INGOLD EFFECT [J].

FORBES, MDE ;

PATTON, JT ;

MYERS, TL ;

MAYNARD, HD ;

SMITH, DW ;

SCHULZ, GR ;

WAGENER, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10978-10980

[7] SYNTHESIS OF CYCLOALKENES VIA ALKYLIDENE-MEDIATED OLEFIN METATHESIS AND CARBONYL OLEFINATION [J].

FU, GC ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (09) :3800-3801

[8] CATALYTIC RING-CLOSING METATHESIS OF FUNCTIONALIZED DIENES BY A RUTHENIUM CARBENE COMPLEX [J].

FU, GC ;

NGUYEN, ST ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) :9856-9857

[9] SYNTHESIS OF NITROGEN-HETEROCYCLES VIA CATALYTIC RING-CLOSING METATHESIS OF DIENES [J].

FU, GC ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (18) :7324-7325

[10] THE APPLICATION OF CATALYTIC RING-CLOSING OLEFIN METATHESIS TO THE SYNTHESIS OF UNSATURATED OXYGEN HETEROCYCLES [J].

FU, GC ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :5426-5427

← 1 2 3 4 5 →