THE STRUCTURE AND DIELECTRIC-PROPERTIES OF POLAR-SOLVENTS

被引:7
作者
FAWCETT, WR
机构
[1] Department of Chemistry, University of California, Davis, CA
关键词
D O I
10.1080/00268979500102311
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The properties of twenty polar solvents are considered with respect to their dielectric permittivities at very low and at optical frequencies. The estimation of the permittivity on the basis of continuum models using the molecular dipole moment and polarizability is discussed. This is compared with the results of a non-primitive model based on the mean spherical approximation. The role of chemical factors in the latter approach is emphasized.
引用
收藏
页码:715 / 724
页数:10
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